The Palette/blue/Made in a lab or a works

Egyptian blue

The first colour humans ever manufactured, invented because the earth does not make blue.

Also called cuprorivaite · caeruleum

Hex
#1034A6
RGB
16, 52, 166
Pigment index
PB31
First used
c.3250 BC
From
Egypt, then the whole Mediterranean

What it is

Calcium copper silicate, CaCuSi₄O₁₀: the mineral cuprorivaite, which is rare in nature and easy to make in a kiln.

How it is made

Sand, a copper source (filings, or ground-up malachite), lime and a flux like natron, mixed and fired at a little over 800°C for several hours. Get the temperature wrong in either direction and you get green glass or an unusable grey frit, which is a narrow window to hold in a wood-fired kiln and tells you how good Egyptian kiln-workers were.

What comes out is a hard blue frit that has to be crushed and ground. The grinding is where the colour is decided: coarse grains give a deep saturated blue, fine grinding turns it pale and chalky. Same material, two different colours, and the only variable is how long somebody stood there with a stone.

Egyptian blue: Egyptian Blue
Egyptian blue: the first colour humans ever manufactured, invented because the earth does not make blue.FK1954/Commons/Public domain

Egyptian blue, Pigment used in ancient Egypt. Wikipedia's description, not ours.


The history

There is no blue earth pigment anywhere on the planet. Red, yellow, brown and black are all lying in the ground in usable quantities; blue is not, and neither is a good green. So the oldest blue in the world is not a discovery, it is an invention, a piece of process chemistry worked out in Egypt in the early dynastic period and used continuously for something like four thousand years.

It spread across the Mediterranean and the Romans called it caeruleum. Vitruvius describes making it in the first century BC. Then the recipe was lost, somewhere around the fall of the Western Empire, and Europe spent the next thousand years without an affordable blue, which is a large part of why medieval blue is either ultramarine at gemstone prices or azurite that goes green.

The strangest part came later. Egyptian blue turns out to emit strong near-infrared light when you shine red light at it, brightly enough that a camera with the right filter can find microscopic traces of it on objects that look completely colourless to the eye. Conservators now use that to recover paintwork on Greek and Roman sculpture that everybody assumed had been white all along. The white classical statue is a mistake, and this pigment is one of the instruments proving it.


Where it is used

Tomb painting, coffin decoration, faience, sculpture, papyri, and the blue on almost any Egyptian object you have seen in a museum. It also painted Greek and Roman marble, which matters more than it sounds: it means the classical world was a coloured world, and the taste for bare white stone is an eighteenth-century idea projected backwards.

For anyone working now, the interesting part is the manufacturing story rather than the pigment. A brand that needs a colour nobody else has does not go looking for a rarer rock; it commissions the colour. That is the same move Yves Klein made in 1957 and the same move a paint company makes when it patents a shade. Egypt got there first by four and a half thousand years.

Go and look at it

  • The painted bust of Nefertiti

    Neues Museum, Berlin

    The blue of the crown is Egyptian blue. Look at how flat and even it sits: a frit ground to a consistent grain, applied like a poster colour rather than blended.

  • Greek and Roman marble sculpture

    Museums everywhere, usually labelled as plain white stone

    Infrared imaging keeps finding this pigment on surfaces that look bare. The stone you are told is classical restraint is a stripped painting.


How it behaves

Made of
Calcium copper silicate, CaCuSi₄O₁₀: the mineral cuprorivaite, which is rare in nature and easy to make in a kiln.
Opacity
Semi-opaque. It covers, but something of the layer beneath still comes through.
Lightfastness
Permanent. It will outlive the thing it is painted on.
  • One of the most stable pigments ever made, four-thousand-year-old examples are still blue.
  • Fluoresces in the near-infrared, which is how conservators find invisible traces of it.
  • Coarse grinding reads deep; fine grinding reads pale. The grind is the colour decision.

The numbers

All derived from the hex, never typed beside it

HEX
#1034A6
What a browser and a design file want.
RGB
16, 52, 166
The same three numbers in base ten. Light, not ink.
HSL
226°, 82%, 36%
Hue, saturation, lightness, how a person describes a colour.
CMYK
90, 69, 0, 35
Arithmetic only. A real separation depends on the press, the paper and a profile.
LAB
28, 34, -64
Perceptual. L* of 28 is how light this actually looks, which HSL gets wrong.

This hex is an approximation, and a page about pigment has to say so. Egyptian blue is a substance. A ground mineral scatters light from thousands of separate grains at slightly different angles, and no single sRGB value is that event. It is a flat average of a photograph of it, and the real thing is outside what a screen can emit. Use the number to specify a screen colour. Do not use it to judge the pigment.

Where it sits on the wheel

Hue 226°

Its opposite, by the diagram

#1034A6
#A68210

The arithmetic opposite, 180° round in HSL. Useful, and not the same as the opposite a painter mixing pigment would name, that wheel was built for paint.

Lighter and darker

Towards white

#1034A6
#3452B3
#5871C1
#889AD3
#B7C2E4
#DBE1F2

Mixing with white does not only lighten, it dulls and cools. This is why a pale tint of a brand colour so often looks chalky, and why a designed light shade beats a generated one.

Towards black

#1034A6
#0E2C8D
#0B2474
#081A53
#051032
#020819

Mixing with black kills the hue as it darkens. A better dark is usually the colour plus its neighbour round the wheel, which is what every painter does instead.

Can you set type on it

Handgloves

White on it
10.18:1 · AAA

Handgloves

Black on it
2.06:1 · Fails

Handgloves

It on paper
9.66:1 · AAA

Handgloves

It on ink
1.80:1 · Fails

4.5:1 is the floor for body text and 3:1 for large text, by WCAG. Treat it as a minimum you may not go under rather than as a target: plenty of pairs pass at 4.6:1 and are still unpleasant to read for a page, and the checker will not tell you that.


Watch

Titles and channels as YouTube reports them

Egyptian Blue: How an Ancient Pigment Could Save Lives · SciShow
The oldest synthetic pigment, Egyptian Blue · Dirty Blue Tube
Synthesizing a Pigment: Egyptian Blue · Newfields


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